 |
 |
 |
|||
 | |||||
 |  |
||
 |
 |
||
 | |||
|
 |
||
| |||
|
 |
||
| |||
|
 |
||
| |||
|
 |
||
| |||
|
 |
||
| |||
|
 |
||
 |
|||
| |||
| |||
|
| Brian Higgins | |
 |
email: bghiggins@ucdavis.edu |
| Office: | |
| Phone: | |
| Professor Emeritus | ||
| B.S., 1972, University of the Witwatersrand M.S., 1975, University of the Witwatersrand Ph.D., 1980, University of Minnesota | ||
Research  | ||
| ||
| Hydrodynamics of Spin Coating: We are studying the hydrodynamics of spin coating of sol gel systems as a method for depositing optical coatings on large area optics. Often, the spin-coated film is nonuniform, characterized by radial striations that extend from the substrate edge to near the substrate center. Experiments in our laboratory have shown that the radial striations are a result of a convective instability. To understand the dynamics of this instability, a linear stability analysis of the time- dependent solutions to the momentum, mass, and energy equations for spin coating is being undertaken. These results are being used to establish operating conditions for stable coatings. Optical Coatings: We are also investigating methods for producing hafnium oxide optical coatings by the sol-gel method from organometallic precursors. The parameters that influence the optical properties and coated thickness are being studied. The dispersion of refractive index of the hafnium oxide coatings is determined from ellipsometry, and transmission spectroscopy. Flow Separation in Thin Film Coatings: Techniques from bifurcation theory are used to study the mechanisms that lead to flow separation in thin film coating flows. Boundary integral and/or Finite Element methods are used to verify the predictions from the theory Sol-Gel Synthesis of Bioactive Nanoscale Silica Particles: Microemulsion technology is used to synthesize nanoscale bioactive silica particles (< 50nm) The water pool provides a chemically favorable \"nano-receptacle\" for the enzyme or other pH-sensitive biomolecules and allows the hydrolysis/condensation reactions leading to particle growth to occur in the vicinity of the enzyme. Control of these reactions through catalyst concentration, surfactant/water ratio, and alkoxide/water ratio determines the particle structure that is required for encapsulation of the enzyme. FTIR is used to elucidate the importance of hydrolysis kinetics on particle size, shape, and porosity. | ||
Laboratories | ||
| The thin film coating laboratory is equipped with several programable spin coaters in walk-in laminar flow hoods. The coaters are optimized so that nanometer scale films can be deposited. We also have glove boxes available for handling moisture sensitive organometallic precursors, furnaces for heat treatment of coated films, and a variety of light microscopes for coated film evaluation. | ||
Support | ||
| California Air Resources Board Chevron Corporation Sony Corporation |
  |
Department | Faculty | Students | Directory | Alumni | Research | Admissions | Contact Us | Webmaster |
| Chemical Engineering and Materials Science Department |